catena-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]
Identifieur interne : 000577 ( Main/Exploration ); précédent : 000576; suivant : 000578catena-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]
Auteurs : Hanène Hemissi [Tunisie] ; Mohammed Rzaigui [Tunisie, Arabie saoudite] ; Zeid Abdullah Al Othman [Arabie saoudite]Source :
- Acta Crystallographica Section E: Structure Reports Online [ 1600-5368 ] ; 2010.
Abstract
The cyclotetraphosphate anion, [P4O12]4−, forms the title complex with cobalt(II) and quinolinium, {(C9H8N)2[Co(P4O12)(H2O)2]·6H2O}
Url:
DOI: 10.1107/S1600536810002096
PubMed: 21579654
PubMed Central: 2979730
Affiliations:
Links toward previous steps (curation, corpus...)
- to stream Pmc, to step Corpus: 000390
- to stream Pmc, to step Curation: 000389
- to stream Pmc, to step Checkpoint: 000315
- to stream Ncbi, to step Merge: 000166
- to stream Ncbi, to step Curation: 000166
- to stream Ncbi, to step Checkpoint: 000166
- to stream Main, to step Merge: 000580
- to stream Main, to step Curation: 000577
Le document en format XML
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-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]</title>
<author><name sortKey="Hemissi, Hanene" sort="Hemissi, Hanene" uniqKey="Hemissi H" first="Hanène" last="Hemissi">Hanène Hemissi</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
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</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<author><name sortKey="Al Othman, Zeid Abdullah" sort="Al Othman, Zeid Abdullah" uniqKey="Al Othman Z" first="Zeid Abdullah" last="Al Othman">Zeid Abdullah Al Othman</name>
<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<idno type="url">http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979730</idno>
<idno type="RBID">PMC:2979730</idno>
<idno type="doi">10.1107/S1600536810002096</idno>
<date when="2010">2010</date>
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<sourceDesc><biblStruct><analytic><title xml:lang="en" level="a" type="main"><italic>catena</italic>
-Poly[diquinolinium [[diaquacobaltate(II)]-μ-cyclotetraphosphato] hexahydrate]</title>
<author><name sortKey="Hemissi, Hanene" sort="Hemissi, Hanene" uniqKey="Hemissi H" first="Hanène" last="Hemissi">Hanène Hemissi</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
<affiliation wicri:level="1"><nlm:aff id="a">Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte,<country>Tunisia</country>
</nlm:aff>
<country xml:lang="fr">Tunisie</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
</affiliation>
</author>
<author><name sortKey="Al Othman, Zeid Abdullah" sort="Al Othman, Zeid Abdullah" uniqKey="Al Othman Z" first="Zeid Abdullah" last="Al Othman">Zeid Abdullah Al Othman</name>
<affiliation wicri:level="1"><nlm:aff id="b">Chemistry Departement, Faculty of Sciences, King Saud University, Riyadh,<country>Saudi Arabia</country>
</nlm:aff>
<country xml:lang="fr">Arabie saoudite</country>
<wicri:regionArea># see nlm:aff country strict</wicri:regionArea>
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<series><title level="j">Acta Crystallographica Section E: Structure Reports Online</title>
<idno type="eISSN">1600-5368</idno>
<imprint><date when="2010">2010</date>
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<front><div type="abstract" xml:lang="en"><p>The cyclotetraphosphate anion, [P<sub>4</sub>
O<sub>12</sub>
]<sup>4−</sup>
, forms the title complex with cobalt(II) and quinolinium, {(C<sub>9</sub>
H<sub>8</sub>
N)<sub>2</sub>
[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]·6H<sub>2</sub>
O}<sub><italic>n</italic>
</sub>
. In the complex anion, the Co<sup>II</sup>
ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water molecules in a slightly distorted octahedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P<sub>4</sub>
O<sub>12</sub>
)(H<sub>2</sub>
O)<sub>2</sub>
]<sup>2−</sup>
}<sub><italic>n</italic>
</sub>
extending along [100]. A network of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds consolidates the crystal packing.</p>
</div>
</front>
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<affiliations><list><country><li>Arabie saoudite</li>
<li>Tunisie</li>
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<name sortKey="Rzaigui, Mohammed" sort="Rzaigui, Mohammed" uniqKey="Rzaigui M" first="Mohammed" last="Rzaigui">Mohammed Rzaigui</name>
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<name sortKey="Al Othman, Zeid Abdullah" sort="Al Othman, Zeid Abdullah" uniqKey="Al Othman Z" first="Zeid Abdullah" last="Al Othman">Zeid Abdullah Al Othman</name>
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