Serveur d'exploration sur le cobalt au Maghreb

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catena-Poly[diquinolinium [[diaqua­cobaltate(II)]-μ-cyclo­tetra­phosphato] hexa­hydrate]

Identifieur interne : 000577 ( Main/Exploration ); précédent : 000576; suivant : 000578

catena-Poly[diquinolinium [[diaqua­cobaltate(II)]-μ-cyclo­tetra­phosphato] hexa­hydrate]

Auteurs : Hanène Hemissi [Tunisie] ; Mohammed Rzaigui [Tunisie, Arabie saoudite] ; Zeid Abdullah Al Othman [Arabie saoudite]

Source :

RBID : PMC:2979730

Abstract

The cyclo­tetra­phosphate anion, [P4O12]4−, forms the title complex with cobalt(II) and quinolinium, {(C9H8N)2[Co(P4O12)(H2O)2]·6H2O}n. In the complex anion, the CoII ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water mol­ecules in a slightly distorted octa­hedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P4O12)(H2O)2]2−}n extending along [100]. A network of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds consolidates the crystal packing.


Url:
DOI: 10.1107/S1600536810002096
PubMed: 21579654
PubMed Central: 2979730


Affiliations:


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-Poly[diquinolinium [[diaqua­cobaltate(II)]-μ-cyclo­tetra­phosphato] hexa­hydrate]</title>
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<p>The cyclo­tetra­phosphate anion, [P
<sub>4</sub>
O
<sub>12</sub>
]
<sup>4−</sup>
, forms the title complex with cobalt(II) and quinolinium, {(C
<sub>9</sub>
H
<sub>8</sub>
N)
<sub>2</sub>
[Co(P
<sub>4</sub>
O
<sub>12</sub>
)(H
<sub>2</sub>
O)
<sub>2</sub>
]·6H
<sub>2</sub>
O}
<sub>
<italic>n</italic>
</sub>
. In the complex anion, the Co
<sup>II</sup>
ion, lying on an inversion center, is surrounded by four phosphate O atoms and two water mol­ecules in a slightly distorted octa­hedral geometry. The crystal structure consists of anionic ribbons of formula {[Co(P
<sub>4</sub>
O
<sub>12</sub>
)(H
<sub>2</sub>
O)
<sub>2</sub>
]
<sup>2−</sup>
}
<sub>
<italic>n</italic>
</sub>
extending along [100]. A network of O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds consolidates the crystal packing.</p>
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